I. Pre-Expedition
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On cruises with short transit times, perform, in port, as many of these the following as possible.:
Lab orientation/Introduction
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- Alkalinity/pH/chloride titrations
- Alkalinity: Prepare 20 mM and 40 mM standards if necessary
- Chlorinity: Prepare 2 liters of dilution solution
- Coulometer
- HCl solution, KOH and AgNO3 solutions if needed
- IC
- all solutions except for anion eluent, which should be made shortly before analysis
- pourable calibration standards
- ICP
- 2% and 3% TM nitric acid solutions, also 10% if doing analyzing hard rock
- internal standard(s)
- primary in-house cocktail
- pourable in-house and IAPSO calibration standards
- SPEC
- Ammonium
- Ammonium standard and (dry ammonium chloride in oven overnight) + calibration standards,
- alkaline solution
- Phosphate
- Phosphate primary standard (dry monobasic potassium phosphate in oven overnight) + calibration standards
- Sulfuric acid solution
- Antimony potassium tartrate solution
- Ammonium molybdate solution
- Ammonium
- Alkalinity/pH/chloride titrations
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- Take a 5 cc headspace sample from every sediment core (non-basement), at the top of a section (try to be consistent). This sample is taken until the total depth objective is met. If doing multiple holes, you do not have to repeat the sampling if a headspace sample has already been taken at that depth but just continue after the prior hole's bottom depth.
- For cores with IW samples, always take the headspace sample adjacent to IW, best from the top of the section immediately below the IW sample. Note the core, section and interval of the headspace sample and write it on the headspace vial. The interval will be entered into SampleMaster by the Curator/ALO.
- Make sure nobody sprays acetone on the catwalk before sampling is completed. Acetone will contaminate the sample.
- It is recommended to occasionally take a sample of the air on the core deck, so that any change in the headspace sample analysis can be correlated to changes in volatilized acetone.
- Inject a standard (corresponding to concentrations seen in the recent cores) every fifty injections or so, to check on the instrument calibration.
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- Set the pressure to 3000 lbs and simultaneously push and hold both green (CLOSE) buttons on the hydraulic unit's base until the auto-pressure engages.
- After the first drops flow from the hole in the squeezer's base plate, insert the syringe into the hole. Keep an eye on the syringe to make sure the pressure doesn't push out the syringe or plunger (especially for the first few cores). Keep incrementing the hydraulic unit pressure in steps of 1000 lbs until 10000 lbs; after 10000 lbs, increase in steps of 2000. Do not ever increase the pressure above 30000 lbs.
- Select the correct core, section and sample in SampleMaster. Upload the IW sample splits (using the Excel template) into SampleMaster and distribute the labels.
- When porewater yield is sufficient/no more water is trickling, release the hydraulic unit pressure by pressing the red OPEN button and remove the syringe from the squeezer.
- Start sample distribution (splits).
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